Biomass Valorization: Sustainable Methods for the Production of Chemicals 1st edition by Davide Ravelli, Chiara Samorì – Ebook PDF Instant Download/DeliveryISBN: 3527825037, 9783527825035
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ISBN-10 : 3527825037
ISBN-13 : 978327825035
Author: Davide Ravelli, Chiara Samorì
Biomass Valorization Explore the potential of biomass-based chemicals with this comprehensive new reference from leading voices in the field With the depletion of fossil raw materials a readily ascertainable inevitability, the exploitation of biomass-based renewable derivatives becomes ever more practical and realistic. In Biomass Valorization: Sustainable Methods for the Production of Chemicals, accomplished researchers and authors Davide Ravelli and Chiara Samori deliver a thorough compilation of state-of-the-art techniques and most advanced strategies used to convert biomass into useful building blocks and commodity chemicals. Each chapter in this collection of insightful papers begins by detailing the core components of the described technology, along with a fulsome description of its advantages and limitations, before moving on to a discussion of recent advancements in the field.
Biomass Valorization: Sustainable Methods for the Production of Chemicals 1st Table of contents:
1 Role of Biomass in the Production of Chemicals
1.1 Introduction
1.2 Biomass Valorization
1.3 Lignocellulosic Biomass
1.4 Key Biomolecules
1.5 Solvents
1.6 Pretreatment of Lignocelluloses
1.7 Conclusions and Perspectives
References
Section I: Catalytic Strategies
2 Biomass Processing via Acid Catalysis
2.1 Introduction
2.2 Acid‐Catalyzed Processing of Cellulosic Polysaccharides
2.3 Acid‐Catalyzed Processing of Lignin
2.4 Conclusions and Perspectives
References
3 Biomass Processing via Base Catalysis
3.1 Introduction
3.2 Aldol Condensation
3.3 Ketonization Reaction of Carboxylic Acids
3.4 Transesterification Reaction
3.5 Conclusions and Perspectives
References
4 Biomass Processing via Metal Catalysis
4.1 Introduction
4.2 Synthetic Strategies for Supported Metal Nanoparticles
4.3 Furfural
4.4 5‐Hydroxymethylfurfural (HMF)
4.5 Conclusions and Perspectives
References
5 Biomass Processing with Biocatalysis
5.1 Introduction
5.2 Generations of Renewable Biomass: Advantages and Limitations
5.3 Advantages and Limitations of Biocatalysis
5.4 Enzyme Discovery and Optimization of Enzyme Performance
5.5 Enzyme Immobilization
5.6 Enzymatic Hydrolysis of Starch to Glucose
5.7 Enzymatic Depolymerization of Lignocellulose
5.8 Enzymatic Hydrolysis of Cellulose and Hemicellulose
5.9 Enzymatic Hydrolysis of 3rd Generation (3G) Polysaccharides
5.10 Commodity Chemicals from Carbohydrates (Monosaccharides)
5.11 Enzymatic Conversions of Triglycerides: Production of Biodiesel and Bulk Chemicals
5.12 Conclusions and Perspectives
References
Section II: Thermal Strategies
6 Biomass Processing via Pyrolysis
6.1 Brief Introduction
6.2 Chemicals from Cellulose Pyrolysis
6.3 Chemicals from Lignin Pyrolysis
6.4 Pyrolysis of Biomass
6.5 Conclusions and Perspectives
References
7 Biomass Processing via Thermochemical–Biological Hybrid Processes
7.1 Introduction
7.2 Pyrolysis Products (PyP) from the Microorganism’s Standpoint
7.3 Conversion of PyP with MMC: Survey of Experimental Evidence
7.4 Feasible Pathways for Producing Chemicals from PyP with MMC
7.5 Conclusions and Perspectives
References
Section III: Advanced/Unconventional Strategies
8 Biomass Processing via Electrochemical Means
8.1 Introduction
8.2 Electrochemical Conversion of Bio‐Based Molecules
8.3 Conversion of Sugars
8.4 Conversion of Furanics
8.5 Conversion of Levulinic Acid
8.6 Conversion of Glycerol
8.7 Lignin Depolymerization
8.8 Scale‐up of Electrosynthesis of Biomass‐Derived Chemicals
8.9 Conclusions and Perspectives
References
9 Biomass Processing via Photochemical Means
9.1 Introduction
9.2 Fundamental Aspects of Photoredox Catalysis
9.3 Photochemical Valorization of Lignin
9.4 Conclusions and Perspectives
References
Note
10 Biomass Processing via Microwave Treatment
10.1 Introduction
10.2 Microwave–Matter Interaction: Advantages and Limitations in the Processing of Biomass
10.3 Microwave Pyrolysis
10.4 Microwave‐assisted Hydrolysis
10.5 Microwave‐assisted Extraction of Phytochemical Compounds
10.6 Conclusions and Perspectives
References
11 Biomass Processing Assisted by Ultrasound
11.1 Introduction
11.2 Ultrasound Background
11.3 Ultrasound‐Assisted Biomass Pretreatments
11.4 Ultrasound‐Assisted Biomass Conversion
11.5 Ultrasound‐Assisted Extraction of Value‐Added Compounds
11.6 Alternative Solvents
11.7 Conclusions and Perspectives
References
12 Biomass Processing via Mechanochemical Means
12.1 Overview and Introduction
12.2 Crystallinity Reduction in Biopolymers via Mechanochemistry
12.3 Mechanochemical Transformations of Polysaccharides
12.4 Mechanochemical Transformations of Amino Acids, Nucleotides, and Related Materials
12.5 Mechanochemical Treatment of Lignin
12.6 Biominerals from Mechanochemical Processing of Biomass
12.7 Conclusions and Perspectives
References
Section IV: Closing Remarks
13 Industrial Perspectives of Biomass Processing
13.1 Replacing Existing Petrochemicals with Alternatives from Biomass: An Introduction
13.2 Oleochemical Biorefinery: A Consolidated and Multifaceted Example of Biomass Processing
13.3 From Sugar to Bio‐monomers: The Case of 2,5‐Furandicarboxylic Acid (FDCA)
13.4 From Bioethanol to Rubber: The Synthesis of Bio‐butadiene
13.5 Conclusions and Perspectives
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Biomass Valorization,Sustainable Methods,the Production of Chemicals,Davide Ravelli,Chiara Samorì