Pericyclic chemistry. Orbital mechanisms and stereochemistry 1st Edition Mandal- Ebook Instant Download/Delivery ISBN(s): 9780128149584,0128149582,9780128149591, 0128149590
Product details:
- ISBN 10:0128149590
- ISBN 13:9780128149591
- Author: Dipak Kumar Mandal
Pericyclic Chemistry: Orbital Mechanisms and Stereochemistry is a complete guide to the topic that is ideal for graduate students, advanced undergraduate students and researchers in organic chemistry. An introduction to molecular orbital theory and relevant stereochemical concepts is provided as background, with all four classes of pericyclic reactions discussed and illustrated with orbital picture representations. Also included are chapters on cycloadditions, the most versatile class, and electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. A separate chapter on the construction of correlation diagrams is also included, emphasizing a practical, hands on approach.
Table contents:
Chapter 1 – Molecular Orbitals
Chapter 2 – Stereochemical Concepts
Chapter 3 – Pericyclic Reactions: Introduction, Classification and the Woodward–Hoffmann Rules
Chapter 4 – Cycloadditions 1: Perturbation Theory of Reactivity, Regioselectivity and Periselectivity
Chapter 5 – Cycloadditions 2: Stereochemistry of [4 + 2] and [2 + 2] Cycloadditions
Chapter 6 – Cycloadditions 3: Cheletropic, Higher Order and Multicomponent Cycloadditions
Chapter 7 – Electrocyclic Reactions: Stereochemistry and Torquoselectivity
Chapter 8 – Sigmatropic Rearrangements 1: [1,j] Shifts
Chapter 9 – Sigmatropic Rearrangements 2: [i,j] Shifts
Chapter 10 – Group Transfer Reactions
Chapter 11 – Correlation Diagrams
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