(Ebook PDF) Silicon Electrochemistry Production Purification and Applications 1st edition by Eimutis Juzeliunas ISBN 9783527831920 3527831924 full chapters

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ISBN 10: 3527831924
ISBN 13: 9783527831920
Author:   Eimutis Juzeliunas

Table of contents:

1 Introduction

• References

2 Silicon Electrochemistry – Toward Low‐Carbon Economy

• 2.1 Silicon for Energy Storage – Electrochemical Batteries
• 2.2 Silicon for Energy Conversion – Photovoltaic Devices
• References

3 Brief Historical Overview of Silicon Production. Metallurgical‐Grade Silicon

• References
• Notes

4 Physical and Chemical Properties of Silicon

• References

5 Silicon Refining: From Metallurgical‐Grade to Electronic‐Grade

• 5.1 Purification Based on Direct Si Chlorination
• 5.2 The Siemens Process
• 5.3 The Union Carbide Process
• 5.4 The Ethyl Process
• 5.5 Electrorefining in Molten Salts
• 5.6 Zone Refining, Acid Leaching
• References

6 Silicon Electrowinning and Electrodeposition of Thin Layers

• 6.1 Electrodeposition in Molten Fluoride, Chloride, and Oxide Electrolytes
• 6.2 Substrate Materials for Silicon Electrodeposition
• 6.3 Electrodeposition of Photoactive Silicon and p–n Junction
• 6.4 Electrodeposition of Silicon from Ionic Liquids and Organic Solvents
• 6.5 Purity Concerns and Solutions
• References
• Notes

7 Photoelectrochemistry and Nanogravimetry of Si and Si‐Oxide Electrodes

• 7.1 Topicality of Si Photoelectrochemical Research
• 7.2 Basic Parameters: Photopotential, Photocurrent, and Photocapacitance
• 7.3 Photoelectrochemical Features of the Si‐Oxide Electrodes
• 7.4 Quartz Crystal Nanogravimetry
• References

8 Electro‐Deoxidation of Solid Compounds in Molten Salts

• References

9 Voltammetry and Basic Reactions of Silicon Electrode in Molten CaCl2

• References

10 Si–SiO2 Electrode in Molten CaCl2

• References

11 Formation of Silicon Oxide Layer

• References

12 In Situ Studies of SiO2 → Si Conversion – Synchrotron X‐ray Diffraction

• References

13 Molten Oxide Electrochemistry at Ultra‐High Temperatures

• References

14 Silicon Surface Structuring

• 14.1 Electrochemical Structuring, Porous Silicon
• 14.2 Chemical–Physical Structuring
• 14.3 Black Silicon
• References

15 Electrochemical Si Surface Structuring and Formation of Black Silicon in High‐Temperature Molten Salts

• 15.1 Anodic and Cathodic Processing in Molten CaCl2
• 15.2 Microcolumnar and Amorphous Structures
• 15.3 Electrodeoxidation of Thin SiO2 Layers
• 15.4 Globular Structures
• 15.5 Black Silicon from Molten Salts
• 15.6 Electrochemical Synthesis of Nanowires: Implications for Li‐Ion Batteries
• References

16 Silicon Compositions – Perspectives for Semiconductor Production

• 16.1 Silicon Carbide
• 16.2 Silicides
• References

17 Silicon Photo‐Electrodes for Water Splitting and Their Protection

• 17.1 Relevance, Basic Principles, and Semiconductor Materials for Photo‐Electrodes
• 17.2 Protection of Silicon Photoelectrodes in Solar‐Fuel Generators
• References

18 Conclusions, Outlook, and Challenges

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